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Calculate the change in entropy when10 kg of water is heated from 900 C to 1000 C.

Solution

Given    Mass of water = 10 kg,   Initial temperature = 900 C = 363 K

                Final temperature = 1000 C = 373 K,                          Specific heat of water = 4180 J/kg K

Asked   Change in entropy, ΔS.

Formulae            ΔQ =mCΔT                          ΔS = ΔQ/T

Here T is the average temperature, in kelvins, of the two bodies in which the heat transfer takes place.

Now, the specific heat of water is the amount of heat required to raise the temperature of 1 kg of water by 10 C. From this we can calculate the heat absorbed to raise the temperature of 10 kg of water by 100 C. Therefore,

ΔQ = 4180 × 10 × 10 = 418000 J (By using the first formula).

Now to find the change in entropy, ΔS, use the 2nd formula. First we find the average temperature.

T = (363 + 373)/2 = 736/2 = 368 K

Now put in the formula,

ΔS = 418000/368 = 1135.9 J K-1

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